Lewis Acid-Promoted Suzuki Reaction using Palladium Chloride Anchored on a Polymer as a Catalyst
Guozhi Fan A B , Hanjun Zhang A , Siqing Cheng A B , Zhandong Ren A , Zhijun Hu A and Zilan Wang AA Department of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, China.
B Corresponding authors. Email: chenchh_2001@126.com; chengsqing@iccas.ac.cn
Australian Journal of Chemistry 61(8) 610-614 https://doi.org/10.1071/CH08066
Submitted: 15 February 2008 Accepted: 22 June 2008 Published: 15 August 2008
Abstract
Palladium chloride anchored on polystyrene modified by 5-amino-1,10-phenanthroline was prepared and used as an efficient recoverable catalyst for Suzuki cross-coupling reactions. The heterogeneous catalysts can be easily separated from the reaction mixture and reused for five cycles without significant Pd leaching and loss of catalytic activity. Rate enhancement in the Suzuki reaction by Lewis acids was also studied.
Acknowledgements
This work was supported by the Hubei Provincial Natural Science Foundation of China (No. 2007ABA369).
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