A Novel Copper Cyanide Complex with a Layered Structure

Xi Liu; Guo-Cong Guo

doi:10.1071/CH08025

RESEARCH ARTICLE

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A Novel Copper Cyanide Complex with a Layered Structure

Xi Liu ^A ^B and Guo-Cong Guo ^A ^C

+ Author Affiliations

- Author Affiliations

^A State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.

^B Key Laboratory of Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 400047, China.

^C Corresponding author. Email: gcguo@fjirsm.ac.cn

Australian Journal of Chemistry 61(7) 481-483 https://doi.org/10.1071/CH08025
Submitted: 23 January 2008 Accepted: 10 April 2008 Published: 16 July 2008

Abstract

The solvothermal reaction of copper(i) cyanide with 18-crown-6 (18C-6) in anhydrous acetonitrile and further diffusion with ether leads to a novel copper cyanide complex Cu(CN)(CH₃CN)·0.5(18C-6) with a rare layered structure that exhibits complex violet luminescence originating from different layers.

Acknowledgements

We gratefully acknowledge financial support of the National Natural Science Foundation of China (20701041), the Natural Science Foundation of Chongqing (CSTC2007BB4234) and the Scientific Project of Chongqing Municipal Education Commission (KJ070812).

References

A Novel Copper Cyanide Complex with a Layered Structure

Abstract

Acknowledgements

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