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Australian Journal of Chemistry Australian Journal of Chemistry Society
An international journal for chemical science
RESEARCH ARTICLE

The Displacement of RSO2 Groups from Tetrahedral Carbon

Stephen Duffy A B and Richard F. Langler A B
+ Author Affiliations
- Author Affiliations

A Department of Chemistry, Mount Allison University, Sackville, New Brunswick, E4 L 1G8, Canada.

B Corresponding authors. Email: sduffy@mta.ca (analytical chemistry); rlangler@mta.ca (organic chemistry)

Australian Journal of Chemistry 61(6) 466-471 https://doi.org/10.1071/CH07237
Submitted: 13 July 2007  Accepted: 27 March 2008   Published: 19 June 2008

Abstract

The first known examples of direct displacement of RSO2 groups from C(sp3) are described. The successful displacements are rationalized in terms of related experimental results and Coulombic stabilization in transition states, anticipated from modern MO computations on ground state structures.


Acknowledgements

The authors acknowledge financial support from Mount Allison University. High-field NMR spectra were obtained by D. Durant.


References


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