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Mono- and Di-nuclear Gold(i) Complexes Containing 1,12-Dicarba-closo-dodecaborane(12)

Joseph A. Ioppolo ^A , Cameron J. Kepert ^A , David J. Price ^A and Louis M. Rendina ^A ^B

+ Author Affiliations

- Author Affiliations

^A School of Chemistry, The University of Sydney, Sydney NSW 2006, Australia.

^B Corresponding author. Email: rendina@chem.usyd.edu.au

Australian Journal of Chemistry 60(11) 816-820 https://doi.org/10.1071/CH07232
Submitted: 6 July 2007 Accepted: 21 September 2007 Published: 1 November 2007

Abstract

The first examples of gold(i) complexes containing monodentate diphenylphosphine-1,12-carborane and bidentate 1,12-bis(diphenylphosphine)-1,12-carborane ligands are reported.

Acknowledgements

We thank Dr Ian Luck and Dr Keith Fisher (The University of Sydney) for assistance with the NMR and ESI-MS studies, respectively. We also thank the Australian Research Council for financial support.

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