One-Dimensional Ag(i) Organometallic Coordination Polymers Generated from a Fulvene-Based Ligand

Peng Wang; Jian-Ping Ma; Ru-Qi Huang; Yu-Bin Dong

doi:10.1071/CH05297

RESEARCH ARTICLE

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One-Dimensional Ag(i) Organometallic Coordination Polymers Generated from a Fulvene-Based Ligand

Peng Wang ^A , Jian-Ping Ma ^A , Ru-Qi Huang ^A and Yu-Bin Dong ^A ^B

+ Author Affiliations

- Author Affiliations

^A College of Chemistry, Chemical Engineering and Materials Science, and Shandong Key Laboratory of Chemical Functional Materials, Shandong Normal University, Jinan 250014, China.

^B Corresponding author. Email: yubindong@sdnu.edu.cn

Australian Journal of Chemistry 59(3) 207-210 https://doi.org/10.1071/CH05297
Submitted: 7 November 2005 Accepted: 25 January 2006 Published: 24 March 2006

Abstract

A new fulvene-based ligand L was synthesized and its coordination chemistry with Ag(i) ion has been investigated. Two novel Ag(i) polymeric complexes, [Ag₂L₂∙5.5(C₆H₆)]SbF₆ (1) and [AgL∙2.5(C₆H₆)]SbF₆ (2), were obtained by combination of L with AgSbF₆ in one-pot reaction. X-Ray single-crystal analysis revealed that both 1 and 2 crystallize in triclinic system P1. In 1 and 2, the ligand L adopts a trans-conformation to bind the Ag(i) centres into a one-dimensional twin-chain structure through either Ag–O coordination or π–π interactions.

Acknowledgments

We are grateful for financial support from the National Natural Science Foundation of China (No. 20371030) and the Shangdong Natural Science Foundation (No. Z2004B01).

References

One-Dimensional Ag(i) Organometallic Coordination Polymers Generated from a Fulvene-Based Ligand

Abstract

Acknowledgments

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