
TY  - JOUR
A1  - Bourke, DG 
A1  - Collins, DJ 
T1  - Synthesis and Some Reactions of 1-(Trimethoxymethyl)cyclohexene
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1996
VL  - 49
IS  - 12
SP  - 1287
EP  - 1291
KW  - 
UR  - https://doi.org/10.1071/CH9961287 
N2  - 1-( Trimethoxymethyl ) cyclohexene (11) was synthesized in three steps from N-methyl-N-phenylcyclohex-1-ene-1-carboxamide (8). Reaction of the &#945;,&#946; -unsaturated ortho ester (11) with sodium hydride and N- methylaniline gave a 1:1 mixture of methyl cyclohex-1-ene-1-carboxylate (15) and N,N- dimethylaniline . Treatment of (11) with 3-methoxyphenol gave 1-[ dimethoxy (3'-methoxyphenoxy)methyl] cyclohexene (10) which underwent thermolysis at 250&#176; to give 1,3-dimethoxybenzene (16) and methyl cyclohex-1-ene-1-carboxylate (15). 
ER  -

