
TY  - JOUR
A1  - Grey, IE 
A1  - Lanyon, MR 
A1  - Stranger, R 
T1  - Structure Characterization of Sulfate and Oxysulfate Phases Formed During Sulfuric Acid Digestion of Ilmenites
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1996
VL  - 49
IS  - 7
SP  - 801
EP  - 815
KW  - 
UR  - https://doi.org/10.1071/CH9960801 
N2  - Laboratory digestion of natural and upgraded ilmenites with concentrated sulfuric acid has been carried out under conditions simulating the sulfate-route pigment process. X-Ray diffraction studies on the solid digestion cakes led to the characterization of a number of different iron titanium sulfate and oxysulfate compounds, whose formation was dependent on the ilmenite composition and digestion conditions. Two different sulfate phases were identified, with structures related to those for Fe2(SO4)3 and H2O[ Zr (HPO4)2]. Four different iron titanium oxysulfates , ( Fe,Ti )(O,OH)SO4, were identified as major digestion products, three having structures related to those for &#946;-NbOPO4, GeOHPO4 and lazulite , Mg[AlOHPO4], and the fourth being a new struture type. The structures of the oxysulfate phases were refined by the Rietveld method. Both the sulfates and the oxysulfates have three-dimensional framework structures formed by corner linking of ( Ti,Fe )O6 octahedra and SO4 tetrahedra, and containing channels or interlayer regions that can be occupied by cations such as H3O+ and Fe2+. The different structures have many features in common. Their structural relationships are discussed and mechanisms are proposed for the phase transformations encountered in the digestion studies. 
ER  -

