
TY  - JOUR
A1  - Beauregard, DA 
A1  - Cambie, RC 
A1  - Dansted, PC 
A1  - Rutledge, PS 
A1  - Woodgate, PD 
T1  - Experiments Directed Towards the Synthesis of Anthracyclinones. XXVI. The Preparation of Chiral Intermediates for Anthracyclinone Synthesis
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1995
VL  - 48
IS  - 3
SP  - 669
EP  - 676
KW  - 
UR  - https://doi.org/10.1071/CH9950669 
N2  - (2&#8242;R)-1,5-Dimethoxy-2(2&#8242;-methyloxiran-2&#8242;-ylmethyl) anthraquinone (8), an intermediate for the synthesis of fridamycin E, has been prepared enantioselectively via the diol (15). The diol (15) was prepared in high yield by asymmetric cis-hydroxylation of the alkene (11). The analogous diol (22), a vineomycinone B2 precursor, was also prepared. 
ER  -

