
%0 Journal Article
%A Campi, EM 
%A Jackson, WR 
%A Mccubbin, QJ 
%A Trnacek, AE 
%T The Stereochemistry of Organometallic Compounds. LXI. The Preparation of Quinazolines and Quinazolinones Involving Rhodium-Catalyzed Hydroformylation of Alkenyl Anilines
%J Australian Journal of Chemistry
%D 1994/06/01
%V 47
%N 6
%P 1061-1070
%K 
%R https://doi.org/10.1071/CH9941061
%U https://www.publish.csiro.au/paper/CH9941061 
%X Rhodium-catalysed reactions of ortho-alkenylaminobenzylamines or benzamides with H2/CO give quinazolines and quinazolinones containing a fused alicyclic ring in excellent yields. Reactions of N- allyl derivatives give a single regioisomer. Reactions of but-3-enyl analogues give readily separable mixtures of pyrrolo and pyrido derivatives. Their 3-methylbut-3-enyl analogues give the pyrido derivatives (12) and (13) in reactions which show unusual diastereoselectivity. 
