
TY  - JOUR
A1  - Bruce, MI 
A1  - Humphrey, PA 
A1  - Surynt, RJ 
A1  - Tiekink, ERT 
T1  - Cluster Chemistry. XCV. Some More Chemistry of Ru<sub>3</sub>(&#956;-dppm )(CO)<sub>10</sub>: Reactions With Allyl Bromide, Dimethyl Disulfide and AuCl(PPh<sub>3</sub>), and Preparation of Some Complexes Containing Tertiary Phosphines and Phosphites. X-Ray Structure of Ru<sub>3</sub>(&#956;-H)(&#956;-SMe)(&#956;-dppm)(CO)<sub>8</sub>
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1994
VL  - 47
IS  - 3
SP  - 477
EP  - 486
KW  - 
UR  - https://doi.org/10.1071/CH9940477 
N2  - Reactions between Ru3(&#956;-dppm )(CO)10 and several reagents have been studied. With allyl bromide, cluster breakup occurs to give binuclear Ru2(&#956;-Br)(&#956;-C3H5)(&#956;- dppm )(CO)4. With Me2S2, binuclear Ru2(&#956;- SMe )2(&#956;- dppm )(CO)4 and trinuclear Ru3(&#956;-H)(&#956;- SMe )(&#956;- dppm )(CO)8 are obtained; the X-ray structure of the latter has been determined. With AuCl (PPh3), addition to one Ru-Ru bond gives AuRu3(&#956;- Cl )(&#956;- dppm )(CO)8(PPh3). Some data on tertiary phosphine substituted products formed in reactions with PMe3, PPh3, P(C6H4Me-3)3, P(C6H4Me-4)3, P( OMe )3, P(OCH2CF3)3, dppe and Fe(&#951;-C5H4PPh2)2 are also given. 
ER  -

