
TY  - JOUR
A1  - Best, WM 
A1  - Dunlop, RW 
A1  - Stick, RV 
A1  - White, ST 
T1  - All About 3,4,6-Tri-O-acetyl-2-deoxy-2-phthalimido-&#946;-D-glucosyl Trichloroacetimidate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1994
VL  - 47
IS  - 3
SP  - 433
EP  - 440
KW  - 
UR  - https://doi.org/10.1071/CH9940433 
N2  - Treatment of 1,3,4,6-tetra-O-acetyl-2-(o-carboxybenzoylamino )-2-deoxy-&#946;-D-glucose with ethyl chloroformate , followed by workup and treatment with methanol, did not give 1,3,4,6-tetra O-acetyl-2-deoxy-2-phthalimido-&#946;-D-glucose as reported in the literature, but rather the methyl ester 1,3,4,6-tetra-O-acetyl-2-deoxy-2-(o- methoxycarbonylbenzoylamino )-&#946;-D-glucose. The formation of this methyl ester is believed to proceed via 1,3,4,6-tetra-O-acetyl-2-deoxy-2- [(3&#8242;-oxo-1&#8242;,3&#8242;-dihydroisobenzofuran-1&#8242;-ylidene)amino]-&#946;-D-glucose which was also formed from the amido carboxylic acid by treatment with dicyclohexylcarbodiimide . Optimal procedures are given for the preparation of the title compound 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-&#946;-D-glucosyl trichloroacetimidate. 
ER  -

