
TY  - JOUR
A1  - Facer, GR 
A1  - Elcombe, MM 
A1  - Kennedy, BJ 
T1  - Bismuth Ruthenium Oxides. Neutron Diffraction and Photoelectron Spectroscopic Study of Bi<sub>2</sub>Ru<sub>2</sub>O<sub>7</sub> and Bi<sub>3</sub>Ru<sub>3</sub>O<sub>11</sub>
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1993
VL  - 46
IS  - 12
SP  - 1897
EP  - 1907
KW  - 
UR  - https://doi.org/10.1071/CH9931897 
N2  - The structures of Bi3Ru3O11, a = 9.3050(2)&#506;, Pn3, and Bi2Ru2O7, a = 10.2957(1)&#506;, Fd3m, have been redetermined by Rietveld analysis of powder neutron diffraction data. For both compounds there is no evidence for appreciable oxygen non- stoichiometry . X-Ray photoelectron spectra of both compounds show unusual line shapes. In the case of Bi3Ru3O11 this is a result of the mixed valency and surface oxidation. In Bi2Ru2O7 final state effects appear to be important. 
ER  -

