
TY  - JOUR
A1  - Corradini, F 
A1  - Marcheselli, L 
A1  - Marchetti, A 
A1  - Tagliazucchi, M 
A1  - Tassi, L 
A1  - Tosi, G 
T1  - A Non-Linear Correlation Model for the Relative Permittivity of Ternary Amphiprotic (Solvent) Mixtures
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1993
VL  - 46
IS  - 10
SP  - 1545
EP  - 1555
KW  - 
UR  - https://doi.org/10.1071/CH9931545 
N2  - Relative permittivities (&#1108;) were determined for ternary ethane-1,2-diol (component 1)/2- methoxyethanol (component 2)/water (component 3) mixtures at five temperatures ranging from 5 to 25&#176;C and over the mole fraction composition range 0 &#8804; Xi &#8804; 1. The data have been fitted to a model equation that could be useful for predictive &#1108; calculations. From the measured &#1108; values, the excess relative permittivity &#1108;E has been evaluated in order to test for three-component adducts. The values of &#1108;E have been found to be negative for all the ternary mixtures under all the experimental conditions, which suggests a strong interaction network through hydrogen bonding, although evidence for a discrete three-component adduct was not forthcoming. 
ER  -

