
TY  - JOUR
A1  - Denys, R 
A1  - Coll, JC 
A1  - Carroll, AR 
A1  - Bowden, BF 
T1  - Tropical Marine Algae. X. Isolaurefucin Methyl Ether, a New Lauroxocane Derivative From the Red Alga <I>Dasyphila plumariodes</I>
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1993
VL  - 46
IS  - 7
SP  - 1073
EP  - 1077
KW  - 
UR  - https://doi.org/10.1071/CH9931073 
N2  - An investigation of the red alga Dasyphila plumariodes resulted in the isolation of the new metabolite isolaurefucin methyl ether [(1S,3R,4S,6S,7S,9S)-4-bromo-3-ethyl-6-methyloxy-9-[(2E)-pent-2-en-4-ynyl]-2,8-dioxabicyclo[5.2.1] decane ] (1), and the previously reported metabolite chlorofucin (2). Complete and unambiguous n.m.r. assignments are provided for (1) and (2). The absolute configuration assigned to (1) is tentative, and is based on its spectral similarity and co-occurrence with (2). 
ER  -

