
%0 Journal Article
%A Tkachev, AV 
%A Rukavishnikov, AV 
%A Chibiryaev, AM 
%A Denisov, AY 
%A Gatilov, YV 
%A Bagryanskaya, IY 
%T Stereochemistry of &#945;-Amino Oximes From the Monoterpene Hydrocarbons Car-3-ene, Limonene and &#945;-Pinene
%J Australian Journal of Chemistry
%D 1992/06/01
%V 45
%N 6
%P 1077-1086
%K 
%R https://doi.org/10.1071/CH9921077
%U https://www.publish.csiro.au/paper/CH9921077 
%X The conformation and configuration of the &#945;-amino oximes derived from the terpene hydrocarbons car-3-ene, limonene and &#945;- pinene have been determined by n.m.r. spectroscopy (high-field 1H n.m.r., 13C n.m.r., INADEQUATE technique), molecular mechanics calculations and X-ray crystallographic analysis. The crystal structure of (lS,3S,6R)-3-dimethylamino-caran-4-one (E)-oxime has been determined by X-ray diffraction; crystals are orthorhombic, space group P 212121 with a 11.421(2), b 13.223(2), c 16.992(4) Å, Z 8. Refinement on 1730 observed reflections measured with Cu K  &#945; radiation converged at R 0.053. 
