
TY  - JOUR
A1  - Hartshorn, RM 
A1  - Sargeson, AM 
T1  - Reactions of Chelated &#946;-Functionalized Amino Acids With Thionyl Chloride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1992
VL  - 45
IS  - 1
SP  - 5
EP  - 20
KW  - 
UR  - https://doi.org/10.1071/CH9920005 
N2  - A variety of bis (ethane-1,2-diamine)cobalt(III) complexes containing chelated  &#946;-functionalized amino acids have been treated with SOCl2 in dimethylformamide. These compounds undergo &#946;-elimination reactions to give chelated enamines followed by either rearrangement to the related imine complexes or further reactions with SOCl2 to give chelated isothiazole-3-carboxylato complexes. Mechanisms are proposed for the reactions. 
ER  -

