
TY  - JOUR
A1  - Di Florio, Romina 
A1  - Rizzacasa, Mark A. 
T1  - Synthesis of the Syributins and Formal Total Synthesis of Syringolide 1.
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2000
VL  - 53
IS  - 4
SP  - 327
EP  - 331
KW  - Amberlyst 15; butenolide; glyceraldehyde acetonide; synthesis; syributin; syringolide.
UR  - https://doi.org/10.1071/CH99170 
N2  - A synthesis of syributins 1 (5) and 2 (6) from D-glyceraldehyde acetonide (12) and furans (14) and (15) is described. Compounds (5) and (6) are cometabolites of the novel non-proteinaceous C-glycosidic elicitor molecules the syringolides 1 (1) and 2 (2). Under a variety of acidic conditions, the intermediate butenolides (9) and (10) provided syributins 1 (5) and 2 (6). Similar results have been reported by Honda and coworkers who converted butenolide (20) into syringolide 1 (1). Since compound (20) was also synthesized by the present new route, a formal synthesis of syringolide 1 (1) has been achieved. 
ER  -

