
TY  - JOUR
A1  - Cambie, RC 
A1  - Grimsdale, AC 
A1  - Rutledge, PS 
A1  - Walker, MF 
A1  - Woodgate, PD 
T1  - Reaction of Podocarpa-6,8,11,13-Tetraenes With m-Chloroperbenzoic Acid and With Dimethyldioxiran: Synthesis of Methyl 6-&#945;,7-&#945;-Epoxy-12-methoxy-podocarpa-8,11,13-trien-19-oate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1991
VL  - 44
IS  - 11
SP  - 1553
EP  - 1573
KW  - 
UR  - https://doi.org/10.1071/CH9911553 
N2  - The reaction of some podocarpa-6,8,11,13-tetraenes with m-chloroperbenzoic acid in either a one-phase system or a two-phase system with an aqueous buffer leads to epoxide-opened products. Successful epoxidations have been achieved in high yield by using the neutral oxidant dimethyldioxiran. The hydroboration -oxidation of methyl 12-benzyloxypodocarpa-6,8,11,13-tetraen-19-oate has been examined. 
ER  -

