
%0 Journal Article
%A Cambie, RC 
%A Grimsdale, AC 
%A Rutledge, PS 
%A Walker, MF 
%A Woodgate, PD 
%T Reaction of Podocarpa-6,8,11,13-Tetraenes With m-Chloroperbenzoic Acid and With Dimethyldioxiran: Synthesis of Methyl 6-&#945;,7-&#945;-Epoxy-12-methoxy-podocarpa-8,11,13-trien-19-oate
%J Australian Journal of Chemistry
%D 1991/11/01
%V 44
%N 11
%P 1553-1573
%K 
%R https://doi.org/10.1071/CH9911553
%U https://www.publish.csiro.au/paper/CH9911553 
%X The reaction of some podocarpa-6,8,11,13-tetraenes with m-chloroperbenzoic acid in either a one-phase system or a two-phase system with an aqueous buffer leads to epoxide-opened products. Successful epoxidations have been achieved in high yield by using the neutral oxidant dimethyldioxiran. The hydroboration -oxidation of methyl 12-benzyloxypodocarpa-6,8,11,13-tetraen-19-oate has been examined. 
