
TY  - JOUR
A1  - Bruce, MI 
A1  - Koutsantonis, GA 
T1  - Cyclopentadienyl-ruthenium and -osmium Chemistry. XXXV. Some Ethynyl, Vinylidene and Related Complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1991
VL  - 44
IS  - 2
SP  - 207
EP  - 217
KW  - 
UR  - https://doi.org/10.1071/CH9910207 
N2  - The syntheses of several vinylidene - and ethynyl -ruthenium complexes are described, starting from HC2SiMe3 and RuCl (L)2(&#951;-C5H5)(L= PPh3, PMe3; L2 = dppe ). Their properties and some reactions are reported. The metallacyclic complex [ Ru {C4H2(SiMe3)2}(PMe3)(&#951;-C5H5)][PF6] has also been isolated. The unsubstituted complexes are very reactive; for example, MeOH adds rapidly to the vinylidene to form the C(OMe)Me derivative. 
ER  -

