
%0 Journal Article
%A Bruce, Michael I. 
%A Skelton, Brian W. 
%A Smith, Mark E. 
%A White, Allan H. 
%T Preparation and Molecular Structures of FcC &#8801; CI and {Co<emph tye="8">2</emph>(CO)<emph tye="8">6</emph>}<emph tye="8">2</emph>(&#181;:&#181;-FcC<emph tye="8">2</emph>C<emph tye="8">2</emph>Fc) [Fc = Ferrocenyl, (<font face = "symbol">h</font>-C<emph tye="8">5</emph>H<emph tye="8">4</emph>)Fe(<font face = "symbol">h</font>-C<emph tye="8">5</emph>H<emph tye="8">5</emph>)]
%J Australian Journal of Chemistry
%D 1999/08/05
%V 52
%N 6
%P 431-436
%K 
%R https://doi.org/10.1071/CH99024
%U https://www.publish.csiro.au/paper/CH99024 
%X Iodination of FcC &#8801; CH with morpholinium iodide gave structurally characterized iodoethynylferrocene, FcC &#8801; CI; its reaction with Co2(CO)8 affords &#123;Co2(CO)6&#125;2(&#181;:&#181;-FcC2C2Fc), also characterized by an X-ray structure determination. This compound is formed by deiodinative coupling of the iodoalkyne and subsequent addition of a Co2(CO)6 group to each C &#8801; C triple bond in the resulting diyne. 
