
TY  - JOUR
A1  - Craig, DC 
A1  - Roberts, NK 
A1  - Tanswell, JL 
T1  - The <I>ortho</I> Metalation of N,N,N',N'-Tetramethyl-P-phenyl-phosphonothioic Diamide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1990
VL  - 43
IS  - 9
SP  - 1487
EP  - 1496
KW  - 
UR  - https://doi.org/10.1071/CH9901487 
N2  - The reaction of C6H5P(S)(NMe2)2 (2) with BuLi in diethyl ether/hexane mixture gives the ortho-metallated species o-LiC6H4P(S)(NMe2)2 (3), which has been characterized by 31P and 13C n.m.r . spectroscopy, and by preparation of the derivatives R{o-C6H4P(S)(NMe2)2}n (where R = Me3Si or Ph2P, n = 1; R = PhP , n = 2; R = P, n = 3). A single-crystal X-ray structure determination of one derivative, phosphinetriyltris (N,N,N&#8242;,N&#8242;- tetramethyl-o-phenylenephosphonothioic diamide ), P{o-C6H4P(S)(NMe2)2}3 (6), is reported. 
ER  -

