
%0 Journal Article
%A Boyd, PDW 
%A Hope, J 
%A Raston, CL 
%A White, AH 
%T Synthesis and Structure of a Binuclear [Bis(ethane-1,2-diamine)nickel(II)]-&#956;-(ethane-1,2-dithiolato)-[(ethane-1,2-dithiolato)Nickel(II)] Complex [Ni(en)<sub>2</sub>(&#956;-C<sub>2</sub>O<sub>2</sub>S<sub>2</sub>)Ni(C<sub>2</sub>O<sub>2</sub>S<sub>2</sub>)], and the Related 3,4-Dimercaptocyclobutene-1,2-dionato Complex
%J Australian Journal of Chemistry
%D 1990/03/01
%V 43
%N 3
%P 601-607
%K 
%R https://doi.org/10.1071/CH9900601
%U https://www.publish.csiro.au/paper/CH9900601 
%X The reaction of planar bis nickel(II) chelates of the ethanebis ( thioate ) ( dithiooxalate ) dianion (C2O2S22-, dto ) or the 3,4-dimercaptocyclobutene-1,2-dionate(2-)( dithiosquarate ) dianion (C4O2S22-, dts ) with bis (ethane-1,2-diamine)nickel(II) dinitrate [NiII (en)2(NO3)2 ]leads to the formation of neutral binuclear complexes of the form [Ni(en)2Ni(L)2] (L= dto or dts ), (1) and (2). An X-ray crystal structure of the dithiooxalate complex has been performed which confirms the formulation of a &#956;- dithiooxalato bridged binuclear complex based on analytical, magnetic and spectroscopic data. The crystals of [Ni(en)2Ni( dto )2] are orthorhombic, space group Pcnn a 8.371(8), b 17.65(1), c 23.37(2)&#506; and Z 8; a total of 853 unique data with I > 2&#963;(I) were refined to R 0.073. The molecule is found to be binuclear with a dithiooxalate dianion bridging a six-coordinate Ni(en)2O2 moiety and a planar four-coordinate Ni( dto )S2 group. 
