
TY  - JOUR
A1  - Bruce, MI 
A1  - Humphrey, MG 
T1  - Reactions of Transition Metal &#963;-Acetylide Complexes. XIII. Alkylation and Related Reactions
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1989
VL  - 42
IS  - 7
SP  - 1067
EP  - 1075
KW  - 
UR  - https://doi.org/10.1071/CH9891067 
N2  - A series of 20 cationic vinylidene complexes of ruthenium and osmium [M(CCRR&#8242;)(L)(L&#8242;)(&#951;- C5H5)]+ (R&#8242; = Me, Ph, C6H4F-4, C6F5, (CH2)2C2H; R&#8242; = Me, CH2Ph, CH2CH=CH2, CH2C2CH, (CH2hBr; L, L&#8242;=PPh3, CNBUT, dppm, dppe; not all combinations), [{Ru (CCRCH2-)(PPH3)2( &#951;- C5H5)2]2+ and [CH2{ CPhCRu (PPh3)2(&#951;-C5H5)]2]2+ have been obtained from reactions between the metal acetylide complexes and the appropriate organic halides. 
ER  -

