
TY  - JOUR
A1  - Gillis, RG 
A1  - Porter, QN 
T1  - Rearrangements in the Molecular-Ions of Some 2,3-Dihydro-1h-1,2-Benzazaphosphole Oxides and Sulfides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1988
VL  - 41
IS  - 7
SP  - 1133
EP  - 1137
KW  - 
UR  - https://doi.org/10.1071/CH9881133 
N2  - The molecular ion of 2-phenyl-2,3-dihydro-1H-1,2-benzazaphosphole oxide undergoes fission of the N-P and P-C bonds in the azaphosphole ring so that C6H5-P=O is lost giving an ion which fragments further to give C8H8N+ (m/z 118). This m/z 118 ion is common to all the compounds studied except those which are not substituted on the nitrogen atom. All the 2,3-dihydro-1H-1,2-benzazaphosphole sulfides lose SH (the oxides do not lose OH); otherwise the 2-phenyl sulfides resemble the 2-phenyl oxides, but the 2-methyl sulfides are quite different from the 2-methyl oxides. 
ER  -

