
TY  - JOUR
A1  - Everest, DJ 
A1  - Grant, PK 
A1  - Slim, GC 
A1  - Yeo, IKL 
T1  - A Mechanism for Anomalous Ozonolysis
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1988
VL  - 41
IS  - 7
SP  - 1025
EP  - 1035
KW  - 
UR  - https://doi.org/10.1071/CH9881025 
N2  - Following the ozonolysis of a series of allylic hydroxy olefins derived from manool (6) we propose a mechanism which accounts for the anomalous ozonolysis products of allylic hydroxyl compounds in nucleophilic and non- nucleophilic solvents. It involves intramolecular participation by the allylic hydroxyl to form a hydroperoxy epoxide rather than the 1,2- nucleophilic migration from carbon to oxygen as proposed in the Criegee rearrangement mechanism. 
ER  -

