
TY  - JOUR
A1  - Laycock, B 
A1  - Maynard, I 
A1  - Wickham, G 
A1  - Kitching, W 
T1  - Silylcuprate Routes to Cyclohex-2-enylsilanes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1988
VL  - 41
IS  - 5
SP  - 693
EP  - 700
KW  - 
UR  - https://doi.org/10.1071/CH9880693 
N2  - The efficacy of the dimethyl(phenyl)silylcuprate and (to a lesser extent) the methyl-diphenylsilylcuprate reagents in converting cyclohex-2-enyl chlorides into the corresponding allylsilanes has been investigated. The presence of copper(I) greatly suppresses formation of the coupled hydrocarbon, and promotes stereo- and regio-selective carbon-silicon bond formation, in a predominantly anti-SN2&#8242; manner. Spectroscopic characterization of the diastereomeric silanes is presented. Grignard routes to some of these silanes are described. 
ER  -

