
TY  - JOUR
A1  - Healy, PC 
A1  - Kildea, JD 
A1  - White, AH 
T1  - Lewis-Base Adducts of Group 11 Metal(I) Compounds. XXIV. 1:2 Silver(I) Halide/Monodentate Amine Complexes: A Novel Structural Type in 1-2 Silver(I) Chloride Piperidine
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1988
VL  - 41
IS  - 3
SP  - 417
EP  - 418
KW  - 
UR  - https://doi.org/10.1071/CH9880417 
N2  - Recrystallization of silver(I) chloride from neat piperidine (L) yields a 1 : 2 adduct, characterized by a single-crystal X-ray study. Crystals are monoclinic, C2/c, a 20.76(4), b 6.422(7), c 20.69(2)&#506;, &#946; 96.9(1)&#176;, Z 8; R 0.042 for 1061 'observed' reflections. The structure, the first determined for a 1 : 2 silver(I) chloride/monodentate amine adduct, is an infinite one-dimensional chloro-bridged polymer -AgL2-Cl-AgL2-Cl-. About the four-coordinate silver atom, Ag-Cl are 2.524(3), 2.667(3)&#506;, Ag-N 2.385(9), 2.347(11)&#506;, with Ag-Cl-Ag 102.62(9)&#176;; the largest angle in the silver environment is 120.3(2)&#176;(Cl-Ag-N). 
ER  -

