
%0 Journal Article
%A Mizerski, W 
%A Kalinowski, MK 
%T Solution Properties of Tetraalkylammonium Halide and Alkali-Metal Halide Ion Pairs. The Relationship Between Dissociation Constants and Solubility Products
%J Australian Journal of Chemistry
%D 1987/07/01
%V 40
%N 7
%P 1201-1209
%K 
%R https://doi.org/10.1071/CH9871201
%U https://www.publish.csiro.au/paper/CH9871201 
%X An empirical relation describing the effect of solvent on the dissociation constant ( Kd ) of ion pairs is described. An equation of the form pKd = apKso + bD-1 + c ( Kso and D stand for the solubility product of a given salt and for the electric permittivity of a solvent, respectively) has been tested with 13 sets of experimental data for salts containing tetraalkylammonium and alkali-metal cations. A successful correlation was obtained in 100% of the cases considered. 
