
TY  - JOUR
A1  - Glover, SA 
A1  - Beckwith, ALJ 
T1  - An E.S.R. Investigation of Ethoxy and Trimethylsilyloxy Iminyl Radicals
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1987
VL  - 40
IS  - 4
SP  - 701
EP  - 709
KW  - 
UR  - https://doi.org/10.1071/CH9870701 
N2  - Trimethylsilyloxy  and ethoxy  iminyls (4a-i) have been generated by photolysis of solutions of the corresponding trimethylsilyl and ethyl N- chloro imidates , in the cavity of an e.s.r. spectrometer. The unpaired electron resides in a 2py orbital on nitrogen in concurrence with the results of MNDO and INDO calculations. The bimolecular rate constants for decay of trimethylsilyloxy t-butyl iminyl (4c) have been evaluated. Trimethylsilyloxy 1,l-dimethylbut-3-enyl iminyl (4e) undergoes an N-C &#948; cyclization. 
ER  -

