
TY  - JOUR
A1  - Dyason, JC 
A1  - Engelhardt, LM 
A1  - Healy, PC 
A1  - Klich, HL 
A1  - White, AH 
T1  - Lewis-Base Adducts of Group 11 Metal(I) Compounds. XXV. Synthesis and Structural Properties of Tris(Triphenylphosphine)Copper(I) Perchlorate and Nitrate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 12
SP  - 2003
EP  - 2011
KW  - 
UR  - https://doi.org/10.1071/CH9862003 
N2  - The compounds (PPh3)3CuOClO3 and (PPh3)3CuONO2(as its mono-ethanol solvate) have been characterized by single-crystal structure analysis. Crystals of the perchlorate are trigonal , P3, a 18.748(8), c 11.731(6)&#506;, Z 3, and are isomorphous with the chloride and tetrafluoroborate structures. R was 0.062 for No = 1452 independent 'observed' reflections. Cu-P distances are 2.314(5), 2.313(7) and 2.317(8)&#506; for each of the three molecules in the unit cell. P-Cu-P angles are 114.5(3), 114.4(3) and 115.6(3)&#176;; Cu-O are 2.32(3), 2.23(3) and 2.23(3)&#506;. Crystals of the nitrate are monoclinic, P21/n, a 14.875(5), b 23.349(7), c 14.141(7) &#506;, &#946; 91.73(3)&#176;, Z 4. R was 0.045 for No = 4066. Cu-P distances are 2.312(2), 2.337(2) and 2.339(2)&#506;; P- Cu-P angles are 114.15(7), 121.37(6) and 113.42(6)&#176;. The nitrate group is monodentate with Cu-O, 2.174(4)&#506; and Cu-O-N, 124.8(4)&#176;. 
ER  -

