
TY  - JOUR
A1  - Broomhead, JA 
A1  - Greenwood, R 
A1  - Pienkowski, W 
A1  - Sterns, M 
T1  - Preparation, X-Ray Crystal-Structure and Properties of Pentacarbonyl-(Pyridinium-2-Thiolate)Tungsten(0)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 11
SP  - 1895
EP  - 1900
KW  - 
UR  - https://doi.org/10.1071/CH9861895 
N2  - The title complex is prepared either photochemically from pyridine-2-thiol and W(CO)6 or thermally from WBr2(CO)4. The molecular structure of this air-stable, diamagnetic compound shows an octahedral environment for the metal. The ligand is sulfur-bound only and the pyridine nitrogen is protonated. Crystals are monoclinic, space group P21/c with a 722.8(1), b 1375.5(4), c 1306.7(2) pm, &#946; 98.815(5)&#176; V 1.2839(5)&#215;109 pm3 and Z 4; 2294 data were refined to R 0.026, Rw 0.032. 
ER  -

