
TY  - JOUR
A1  - Duggan, LL 
A1  - Hitchman, MA 
T1  - Electron-Paramagnetic-Res Spectra of Cu<sup>2+</sup> Doped Potassium Tetranitroplatinate(II)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 9
SP  - 1321
EP  - 1329
KW  - 
UR  - https://doi.org/10.1071/CH9861321 
N2  - The e.p.r . spectrum of Cu2+ doped into single crystals of K2Pt(NO2)4 is reported. In contrast to the host lattice, which contains four nitrogen-bonded nitrite groups, superhyperfine structure due to coupling with the nitrogen nuclear spins suggests that the guest Cu(NO2)42- complex contains two nitrites bonded through nitrogen, and two coordinated through oxygens probably asymmetrically chelated . The likely structure and orientation of the copper(II) complex is discussed, and the g and A tensors are interpreted in terms of the ground-state wavefunction parameters. 
ER  -

