
TY  - JOUR
A1  - Elliott, RL 
A1  - Nichols, PJ 
A1  - West, BO 
T1  - Synthesis of Heterobinuclear Oxo-Bridged Compounds of Chromium, Iron, Manganese and Molybdenum
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 7
SP  - 975
EP  - 985
KW  - 
UR  - https://doi.org/10.1071/CH9860975 
N2  - The synthesis of a series of heterobinuclear oxo -bridged compounds has been accomplished by redox reactions between FeII or MnII complexes of pentadentate and tetradentate salicylideneimines and thiosalicylideneimines and bidentate  dithiocarbamates and either CrIVO ( tpp )( tpp &#8801; dianion of 5,10,15,20-tetraphenylporphyrin) or MoVI (O)2( dtc )2 ( dtc &#8801; diethyldithiocarbamato anion). The compounds are stable in solution in the absence of air but yield various homonuclear derivatives of the metals in its presence, these results indicating a degree of disproportionation of the oxo complexes. The compounds show reduced magnetic moments in line with magnetic coupling between the metal centres. 
ER  -

