
TY  - JOUR
A1  - Picker, K 
A1  - Proust, SM 
A1  - Ridley, DD 
T1  - Diels-Alder Reactions With Unsaturated Sulfoxides. Reactions of (Z)-3-Phenylsulfinylprop-2-Enoic Acid and Methyl-Ester With Furan, 1,3-Diphenylisobenzofuran and Anthracene
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 4
SP  - 575
EP  - 589
KW  - 
UR  - https://doi.org/10.1071/CH9860575 
N2  - Methyl (Z)-3-phenylsulfinylprop-2-enoate undergoes Diels -Alder reactions with furan, 1,3-diphenylisobenzofuran and anthracene but chemical and stereochemical courses of the reactions are very dependent upon reaction conditions. Thus, with furan, cis,endo - and cis,exo - adducts are formed exclusively; with 1,3-diphenylisobenzofuran cis,endo - and cis,exo -adducts are formed at low temperatures, whilst the corresponding trans-adducts are formed upon heating; with anthracene where high temperatures are required for condensation cis- and trans-adducts arise together with products from further thermal reactions. 
ER  -

