
TY  - JOUR
A1  - Mak, TCW 
A1  - Yip, WH 
A1  - Kennard, CHL 
A1  - Smith, G 
A1  - Oreilly, EJ 
T1  - The Crystal-Structure of Silver(I) (2-Carbamoylphenoxy)Acetate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 3
SP  - 541
EP  - 546
KW  - 
UR  - https://doi.org/10.1071/CH9860541 
N2  - The crystal structure of anhydrous silver(I)(2-carbamoylphenoxy)acetate has been determined by X-ray diffraction and refined to a residual of 0.041 for 1532 observed reflections. The complex forms crystal: with space group C2/c and Z4 in a unit cell of dimensions a 20.789(6), b 5.202(1) c 17.318(6)&#506;, &#946; 105.89(2)&#176;. The structure is based on a centrosymmetric bis-carboxylate bridged dimer [Ag-O 2.228(3), 2.266(3)&#506;, O-Ag-O 155.8(1)&#176;; Ag&#8230;Ag 3.001(1)&#506;] which is extended into an infinite zigzag polymer through the axial positions via the carbamoyl oxygens of adjacent ligands [Ag-O 2.494(3)&#506;]. Symmetrical long-rang interactions of phenyl-carbon to silver are also found in the structure [Ag-C 3.094, 3.078(4)&#506;]. 
ER  -

