
TY  - JOUR
A1  - Bruce, MI 
A1  - Duffy, DN 
A1  - Humphrey, MG 
T1  - Reactions of Transition-Metal Sigma-Acetylides. V. Synthesis and X-Ray Structure of Co<sub>2</sub>(µ-&#951;<sup>2</sup>-PhC<sub>2</sub>Fe(Co)<sub>2</sub>(&#951;-C<sub>5</sub>h<sub>5</sub>))(Co)<sub>6</sub>
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 1
SP  - 159
EP  - 163
KW  - 
UR  - https://doi.org/10.1071/CH9860159 
N2  - The reaction between Co2(CO)8 and Fe(C2Ph)(CO)2(&#951;-C5H5) gave the title complex in 44% yield. The molecular structure was determined from a single-crystal X-ray diffraction study, and consists of the transition metal acetylide acting as a conventional &#956;- alkyne  ligand to a Co2(CO)6 unit. Crystals are monoclinic, space group P21/n, with a 11.610(8), b 14.657(4), c 12.526(6)&#506;, &#946; 90.30(5)&#176;, and Z 4; 1683 independent data were refined to R 0.080, Rw 0.087. 
ER  -

