
%0 Journal Article
%A Bruce, MI 
%A Duffy, DN 
%A Humphrey, MG 
%T Reactions of Transition-Metal Sigma-Acetylides. V. Synthesis and X-Ray Structure of Co<sub>2</sub>(µ-&#951;<sup>2</sup>-PhC<sub>2</sub>Fe(Co)<sub>2</sub>(&#951;-C<sub>5</sub>h<sub>5</sub>))(Co)<sub>6</sub>
%J Australian Journal of Chemistry
%D 1986/01/01
%V 39
%N 1
%P 159-163
%K 
%R https://doi.org/10.1071/CH9860159
%U https://www.publish.csiro.au/paper/CH9860159 
%X The reaction between Co2(CO)8 and Fe(C2Ph)(CO)2(&#951;-C5H5) gave the title complex in 44% yield. The molecular structure was determined from a single-crystal X-ray diffraction study, and consists of the transition metal acetylide acting as a conventional &#956;- alkyne  ligand to a Co2(CO)6 unit. Crystals are monoclinic, space group P21/n, with a 11.610(8), b 14.657(4), c 12.526(6)&#506;, &#946; 90.30(5)&#176;, and Z 4; 1683 independent data were refined to R 0.080, Rw 0.087. 
