
TY  - JOUR
A1  - Hambley, TW 
A1  - Raguse, B 
A1  - Ridley, DD 
T1  - Preparation and Crystal Structure of the Unusual Palladium(II) Chloride/Optically Active Sulfoxide Complex: µ-[(R,R)-1,5-Bis{o-(p-toluenesulfinyl)phenoxy}-3-oxapentane]-bis(µ-chloro)-dichlorodipalladium Dichloromethane Solvate, [Pd<sub>2</sub>C<sub>l4</sub>(C<sub>30</sub>H<sub>30</sub>O<sub>5</sub>S<sub>2</sub>)].(CH<sub>2</sub>Cl<sub>2</sub>)<sub>2</sub>
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1985
VL  - 38
IS  - 10
SP  - 1455
EP  - 1460
KW  - 
UR  - https://doi.org/10.1071/CH9851455 
N2  - A complex between palladium(II) chloride and the optically active podand , (S,S)-1,5-bis[o-(p- toluenesulfinyl ) phenoxy ]-3-oxapentane, has been prepared and is shown to contain two equivalents of palladium(II) chloride to one equivalent of the podand. Crystal structure analysis shows each of the sulfur atoms in the sulfoxide groups is coordinated to a palladium atom, and the palladium atoms are also linked through chloride bridges. Crystal data: a 14.878(2), b 17.226(3), c 8.178(1) &#506;, &#946; 103.30(1)&#176;; P21; Z 2. 
ER  -

