
TY  - JOUR
A1  - Kildea, JD 
A1  - Skelton, BW 
A1  - White, AH 
T1  - Crystallographic Characterization of a Hydrated Form of Copper(I) Cyanide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1985
VL  - 38
IS  - 9
SP  - 1329
EP  - 1334
KW  - 
UR  - https://doi.org/10.1071/CH9851329 
N2  - The crystal structure of a crystalline artefact of a reaction involving copper(I), cyanide and water under conditions of high temperature and pressure has been determined by single-crystal X-ray diffraction methods at 295 K, and refined by full matrix least-squares to a residual of 0.046 for 572 independent 'observed' reflections; the composition is suggested to be [Cu3(CN)3(H2O)]&#8734;, comprising a two- dimensional polymer with both linearly coordinated and bridging cyanide groups. Crystals are monoclinic, probable space group C2/c, a 19.048(7), b 6.798(3), c 13.223(7) &#506;, &#946; 125.72(3)&#176;, Z 8. 
ER  -

