
TY  - JOUR
A1  - Creaser, II 
A1  - Dubs, RV 
A1  - Sargeson, AM 
T1  - The base hydrolysis of coordinated fluorophosphate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 10
SP  - 1999
EP  - 2003
KW  - 
UR  - https://doi.org/10.1071/CH9841999 
N2  - [(NH3)5CoO3PF]+ undergoes base hydrolysis in 0.1-0.3 M NaOH, µ = 1.0, at 25ºC to generate free FPO32-, F- and [(NH3)4Co(OH)(NH2PO3)] with a second-order rate constant k2 3.3 &#215; 10 mol-1 s-1 where k2 is the composite rate constant for FPO32- release and hydrolysis of F- with the two products being formed in approximately equal amounts. The measured rate constitutes an estimated enhancement of about 1010 over the base hydrolysis of the uncoordinated FPO32- ion under the same conditions when the concentration of the coordinated nucleophile is taken into account. 
ER  -

