
%0 Journal Article
%A Black, DSC 
%A Johnstone, LM 
%T Nitrones and oxaziridines. XXXII. Some reactions of bicyclic 1-pyrroline 1-oxides
%J Australian Journal of Chemistry
%D 1984/03/01
%V 37
%N 3
%P 577-585
%K 
%R https://doi.org/10.1071/CH9840577
%U https://www.publish.csiro.au/paper/CH9840577 
%X Oxidation of the bicyclic nitrone (2) with nitric acid gave the nitro diketone (3). Bridgehead hydroxylation was achieved by conversion of the nitrones (1), (2) and (8) into the imino-benzoates (4), (5) and (9) respectively with benzoyl chloride and subsequent base hydrolysis to give the hydroxy-imines (6), (7) and (10) respectively. Photoirradiation of the bicyclic nitrone (2) gave the oxaziridine (14), which on further irradiation gave the fused azetidine (15) and the fused pyrroline (16). 
