
TY  - JOUR
A1  - Hambley, TW 
A1  - Lawrance, GA 
T1  - <I>cis</I>-Aquachlorobis(ethane-1,2-diamine)ruthenium(III) trifluoromethanesulfonate: Crystal structure and hydrolysis kinetics
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 2
SP  - 435
EP  - 441
KW  - 
UR  - https://doi.org/10.1071/CH9840435 
N2  - The pale yellow ruthenium(III) complex cis-[Ru(H2NCH2CH2NH2)2(OH2)Cl] (CF3S03)2.H2O crystallized in the space group P1, a 11.661(2), b 9.961(2), c 9.130(2) Å, &#945; 78.83(3), &#946;70.42(2), &#947; 85.29(2)º, Z 2. The Ru-N, Ru-Cl and Ru-O bond distances in the essentially octahedral ion are 2.10 (average), 2.323(1) and 2.093(2) Å respectively. The complex hydrolyses with retention of configuration in aqueous acid (0.01 M HOSO2CF3, kaq 2.70 x 10-5S-1 at 25ºC, &#8710;H ? 90.6(± 1.5) kJ mol-1, &#8710;S ?-28 (± 5) 5 K-1 mol-1) and base (0.01 M NaOH, koh 0.44 mol-1 1. s-1 at 25ºC, &#8710;H&#8225; 73.5(± 2.0) kJ mol-1, &#8710;S&#8225;-43(± 7) JK-1 mol-1). 
ER  -

