
TY  - JOUR
A1  - Boyd, IW 
A1  - Wedd, AG 
T1  - Oxomolybdenum(V) complexes with Quinolin-8-olato, Quinoline-8-thiolato and Quinolin-8-aminato ligands
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 2
SP  - 293
EP  - 301
KW  - 
UR  - https://doi.org/10.1071/CH9840293 
N2  - The mononuclear complexes [MoVOXL2] (X = Cl, Br; LH = quinolin-8-ol, quinoline-8-thiol) have been synthesized from the reaction of (pyH)2 [MoOCl5] and (pyH) [MoOBr4] with quinolin-8-ol or 8-mercaptoquinolinium chloride and bromide in the presence of NEt3 or NaOMe. Bromine superhyperfine coupling [A(79,81Br) 7 &#215; 10-4 cm-1] is observed in the e.s.r. spectra of [MoOBrL2]. The reaction of (pyH)2 [MoOCl5] with quinolin-8-amine (LH) and water produces binuclear [Mo2O3Cl2L2]. 
ER  -

