
TY  - JOUR
A1  - Hewitt, DG 
A1  - Teese, MW 
T1  - Organophosphorus chemistry. III. Synthesis of 3-Ethoxy-2-phenyl-1,3-azaphosphininane 3-oxide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 1
SP  - 205
EP  - 210
KW  - 
UR  - https://doi.org/10.1071/CH9840205 
N2  - Treatment of ethyl (3-bromopropyl)phosphonochloridate with benzylmagnesium chloride gave ethyl (benzyl)(3-bromopropyl)phosphinate. This underwent free-radical bromination to give ethyl (a-bromobenzyl)(3-bromopropyl)phosphinate Cyclization with aqueous ammonia gave 3-ethoxy- 2-phenyl-1,3-azaphosphininane 3-oxide. Attempts to prepare the 2-(pyridin-3'-yl)-substituted 1,3-azaphosphininane are also discussed. 
ER  -

