
TY  - JOUR
A1  - Burgess, AK 
A1  - Young, CL 
T1  - The phase behaviour of binary mixtures containing hydrogen
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1983
VL  - 36
IS  - 10
SP  - 2005
EP  - 2017
KW  - 
UR  - https://doi.org/10.1071/CH9832005 
N2  - The solubility and gas-liquid critical temperatures of mixtures of hydrogen with the permanent gases has been discussed in terms of the one-fluid model and 'hard sphere + attractive term' equations of state as proposed by Carnahan and Starling and Guggenheim. The solubilities of hydrogen and 'moderately-sized' hydrocarbons such as benzene and cyclohexane and higher hydrocarbons such as decalin and bicyclohexyl have also been discussed in terms of the one-fluid model. Finally, examples of the solubilities of other small molecules, methane, nitrogen and carbon dioxide, in both 'moderately sized' and higher hydrocarbons are considered in terms of the one-fluid model. It is concluded that : (A) The best fit values of the interaction parameter, &#950;, for all mixtures, except the permanent gas+ hydrogen systems, are considerably smaller than predicted by the Hudson and McCoubrey rule. (B) The values of &#950; for the hydrogen+ hydrocarbon mixtures are considerably smaller than those for similar hydrocarbons + other small molecules. (c) Often the best fit value of &#950; decreases with an increase in temperature. 
ER  -

