
%0 Journal Article
%A Burgess, AK 
%A Young, CL 
%T The phase behaviour of binary mixtures containing hydrogen
%J Australian Journal of Chemistry
%D 1983/10/01
%V 36
%N 10
%P 2005-2017
%K 
%R https://doi.org/10.1071/CH9832005
%U https://www.publish.csiro.au/paper/CH9832005 
%X The solubility and gas-liquid critical temperatures of mixtures of hydrogen with the permanent gases has been discussed in terms of the one-fluid model and 'hard sphere + attractive term' equations of state as proposed by Carnahan and Starling and Guggenheim. The solubilities of hydrogen and 'moderately-sized' hydrocarbons such as benzene and cyclohexane and higher hydrocarbons such as decalin and bicyclohexyl have also been discussed in terms of the one-fluid model. Finally, examples of the solubilities of other small molecules, methane, nitrogen and carbon dioxide, in both 'moderately sized' and higher hydrocarbons are considered in terms of the one-fluid model. It is concluded that : (A) The best fit values of the interaction parameter, &#950;, for all mixtures, except the permanent gas+ hydrogen systems, are considerably smaller than predicted by the Hudson and McCoubrey rule. (B) The values of &#950; for the hydrogen+ hydrocarbon mixtures are considerably smaller than those for similar hydrocarbons + other small molecules. (c) Often the best fit value of &#950; decreases with an increase in temperature. 
