
TY  - JOUR
A1  - Figgis, BN 
A1  - Kucharski, ES 
A1  - White, AH 
T1  - Crystal structure of Bis(2,2':6',2''-terpyridyl)cobalt(III) chloride
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1983
VL  - 36
IS  - 8
SP  - 1563
EP  - 1571
KW  - 
UR  - https://doi.org/10.1071/CH9831563 
N2  - The crystal structure of the title compound [CO(C15H11N3)2]Cl3 has been determined by single crystal X-ray diffraction methods at 295 K and refined by least-squares methods to a residual of 0.069 for 2953 'observed' reflections. Crystals are triclinic, PI, a 9.018(4), b 11.751(4), c 18.085(6)Å, &#945; 9O.82(6), &#946; 9O.66(7), &#947; 90.79(7)º, Z 2. The determination establishes for the first time metal-nitrogen distances in the bis(terpyridyl)cobalt(III) species; (Co-N)(central, distal) are 1.86, 1.93 Å. The precision of the determination is adversely affected by widespread solvent/anion disorder. 
ER  -

