
TY  - JOUR
A1  - Abushamleh, AS 
A1  - Goodwin, HA 
T1  - Metal complexes of 1,10-phenanthroline derivatives. XIII. Denitrogenation in complexes of 2-hydrazino-1,10-phenanthroline
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1982
VL  - 35
IS  - 5
SP  - 1053
EP  - 1056
KW  - 
UR  - https://doi.org/10.1071/CH9821053 
N2  - Interaction of 2-hydrazino-1,10-phenanthroline (L) with iron(III) or copper(II) salts results in oxidation of the ligand through loss of nitrogen and complexation of the oxidation product, 1,10-phenanthroline. The mixed iron(II)/iron(III) complex [Fe(phen)3] [FeCl4]2, identified by its magnetic and spectral properties, is formed from the reaction with iron(III) and pure [Cu(phen)2] [BF4]2 is obtained from the reaction with copper(II) fluoroborate. Slow denitrogenation of [FeL2] [BF4]2 has been observed in the solid state. 
ER  -

