
TY  - JOUR
A1  - Blunt, JW 
A1  - Coxon, JM 
A1  - Gibson, JR 
T1  - Conformational dynamics of three substituted decahydronaphthalenes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1981
VL  - 34
IS  - 11
SP  - 2469
EP  - 2473
KW  - 
UR  - https://doi.org/10.1071/CH9812469 
N2  - The thermodynamic parameters for equilibrium of the chair-chair conformational enantiomorphs of 8a-methyl-cis-decahydronaphthalen-4a-yl acetate, Ea 67.1 ± 3 kJ mol-1, &#916;H&#8225; 64.5 ± 3 kJ mol-1,4a-chloro-8a-methyl-cis-decahydronaphthalene, Ea 73.6 ± 2.5 kJ mol-1, &#916;H&#8225; 70.8 ± 2.5 kJ mol-1 and the chair-chair conformers of (1&#945;,4a&#945;,8a&#945;)-4a-methyldecahydronaphthalene-1,8a-diyl diacetate:conformer (A) to (B) Ea 68.9 ± 4 kJ mol-1, &#916;H&#8225; 66.7 ± 4 kJ mol-1, and conformer (B) to (A) Ea 66.8 ± 4 kJ mol-1, &#916;H&#8225; 64.5 ± 4 kJ mol-1 have been determined from 13C n.m.r. studies. 
ER  -

